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Mercury
Work Group
Phase I Reports >> End of Pipe Report
Executive Summary | End-of-Pipe Report |
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For more information,
contact David Eppstein by email at
deppstein@masco.harvard.edu,
or by calling 617-632-2860.
Vendor
Interviews & Data Acquisition
The next task of the
Subcommittee was to interview suppliers of all of the identified
technologies to determine whether individual components or even
combinations of available techniques could be used for mercury
removal following simple neutralization. The goal of the
interview process was not just to hear proposed strategies for a
system but, also, to determine where a technology may have
already been applied to mercury removal from a hospital
wastestream. The following presents a summary of presentations
made to or reviewed by the Subcommittee over its tenure:
MWRA Mercury
Workshop on June 13, 1994:
Case studies were
presented that seemed to highlight the issues which we were
about to discuss in our meetings, i.e., the technology is not
readily available and that which is available is extremely
costly and usually applicable only to relatively low flow rates.
Briefly, the following summarizes the highlights of the various
presentations:
Dupont: facility
is approximately 150,000 square feet in size and generates a
maximum of 3,000 gallons per week of wastewater though 400 to
500 gallons per week is more realistic. They have developed a
process which employs a membrane microfilter (type) filter press
for solids extraction following chemical conditioning of the
influent wastestream (method not discussed). The use of
activated carbon was discounted on the basis of reduced capacity
(premature exhaustion) due to competition for adsorption by
organics. For this flow rate, their technology costs about
$100,000. The facility has spent about $500,000 to date in
attempting to come into compliance with the MWRA's
"Prohibited" standard (source reduction measures,
repiping and the IWWT system).
K-Bro Laundry:
Commercial laundry serving the hospitals and discharging some
66,000 gallons per day. Primary source of mercury was traced to
wastewater pretreatment reagents (bleach and sulfuric acid) and
mercury thermometers received with the hospital linens. One
thermometer received in the linens was analyzed and found to
contain some 527 milligrams of mercury. This was sufficient to
put the facility into noncompliance for two days. Facility is
attempting to comply with an employee education process and
ongoing negotiations with the MWRA.
US Army, Natick
Labs: John Manning described their efforts on the mercury
issue dating back to 1988. The facility is comprised of some 30
to 40 buildings and generates about 160,000 gallons per day of
wastewater. The facility was sued by the Massachusetts Attorney
General's office for Clean Water Act violations (mercury) in
1992. To date, 200 traps have been tested with 90% registering
positive (above 1.0 ppb). Many have been cleaned, replaced or
decommissioned. Limestone chip neutralization tanks (two at
1,500 gallons in size and one at 7,000 gallons in size) have
been cleaned with contents verified as mercury contaminated and,
in fact, the marble chips themselves , verified to contain
mercury. Efforts at trap cleaning involved the use of 2% sodium
hypochlorite in contact for 2 hours followed by brush cleaning
and wiping. Traps made of copper and/or lead were replaced since
research showed an amalgam being formed with the mercury which
could not be removed but would continue to leach mercury into
the effluent stream. Efforts at horizontal run pipe cleaning
have not yet been attempted. To date, this facility has expended
approximately $1,000,000 on the issue and is still under
enforcement by the AG's office with further plans still in the
offing on how they might eventually come into compliance.
TURI/OTA: John
Raschco described the efforts of a "large analytical
testing laboratory" (approximately 250 people) to come into
compliance with the MWRA mercury discharge standard. The lab
produces some 1,800 gallons per day of wastewater which
initially contained about 300 ppb of mercury. Through source
control measures, this concentration was lowered by 90% to
approximately 30 ppb but this level is still 30 times over the
MWRA's requirement of 1.0 ppb. The final solution, according to
the speaker, was to install an IWWT system using silver
impregnated activated carbon (total of six contactors, each
containing 5 cubic feet of media) preceded by flow equalization,
5 micron bag filters, UV sterilization and pH adjustment and
followed by final pH adjustment and monitoring (pH & flow).
The system, as described, has a capacity of 1,800 gallons per
day and was installed at a cost of approximately $100,000.
Breakthrough of the carbon contactors was stated to be between
two to three weeks at average flow. The useful life of each
carbon contactor, therefore, is about 600 gallons at which point
the carbon is removed from service and disposed off-site as a
hazardous waste. Using these figures, projected operating costs
(purchase and disposal) for the main component of this system
(carbon contactors) alone are on the order of $150,000 to
$200,000 annually based on an 1,800 gallon per day flowrate.
Minutes of October
26, 1994 Meeting:
A. A presentation was
made by NTEC, Inc. (later the name was changed to Solmetex):
Copies of technical
papers applicable to the technology had been previously
submitted and are on file. The technology was reported to be
adaptable to a wide range of flows using a proprietary mechanism
of covalent bonding not unlike ion exchange though the
presenters emphasized that it was not. The technology has
primary applicability as a tertiary polishing step following
some other primary pretreatment technology. The NTEC system is
most useful in the treatment of wastewater with an influent
(dissolved) mercury concentration of less than 50 ppb. A removal
efficiency to less than 1.0 ppb was claimed.
The system is
susceptible to fouling by suspended solids so prefiltration is
necessary. The system is also preferential to iron loading which
may lead to premature exhaustion. No negative operating impacts
due to pH variations, temperature, chlorine, reducers or organic
solvents were claimed. The system does not provide for bacterial
decontamination. The system can be customized for scavenging
other selected metals (chromium, copper, etc.). Automatic
regeneration with caustic (1 BV) and sulfuric acid (2 BV) to an
electrolytic plate-out cell is incorporated into the design.
Operating pressure across the exchange media is 50 psig with a
nearly instantaneous pollutant exchange (minimal residence time)
obtained. Column breakthru is monitored by bed volume loading
and an assumption of influent metals concentration though NTEC
is investigation in-line monitoring of conductivity as a
measurement of column exhaustion. Parallel operation is
suggested to help minimize down time during periods of system
regeneration.
B. A presentation was
made by Water Stop:
The system is custom
designed and uses a proprietary KDF (zinc-copper alloy) exchange
media followed by anion and cation exchange (disposable)
polishing columns that can be operated in a series or parallel
mode, as desired. The system is typically applied following a pH
neutralization system so would be considered a polishing module.
Some problems in the basic system design relative to an
inability to handle hydraulic fluctuations, power failures and
periods of system maintenance were uncovered during the
presentation which Water Stop will have to address before this
design can be considered further by the End of Pipe
Subcommittee.
Minutes of November
16, 1994 Meeting:
A presentation was made
by U.S. Filter:
US Filter explained
that it represents a family of water and wastewater pretreatment
companies including, IWT, Ionpure, Lancy, LYCO, Membralox,
PERMUTITT, Recovery Services and Superblue. These individual
companies have the capability to deliver systems (packaged or
customized) which use technologies such as simple filtration,
physico-chemical processes, tertiary chemical, ion-exchange and
membrane separation processes. They explained that the
technology proposed for addressing the mercury issue would need
to meet the specifics of the application. To this end, US Filter
requested that the Subcommittee prepare and submit wastewater
profiles from its members for review and evaluation.
NOTE: Action
required by any participating member institution: Information
should include parameters such as flow (total daily and
distribution (%) by shift), heavy metals (including mercury, by
species if available), petroleum hydrocarbons (PHC or TPH),
oil/grease (FOG), organic solvents (EPA Methods 624 & 625),
TSS, TDS, BOD, COD, phosphate, ammonia and alkalinity. As a
starting point, the Subcommittee suggests that members compile
available results from recent MWRA SMART reports submitted under
Industrial User Discharge Permits. This information should be
compiled and made available as soon as possible (mail or fax:)
but not later than November 28, 1994. All submitted
reports will be sanitized (host facility name and identifying
information removed) prior to distribution to system suppliers.
Following data receipt,
US Filter indicated that a preliminary evaluation of suitable
technologies would be developed for subsequent evaluation.
Depending upon the type(s) of technologies suggested, five (5)
gallon samples of untreated wastewater from the member
institutions would be collected (NOTE: Action required by
any participating member institution) and sent to US
Filter/Lancy Division for completion of bench top screening
tests. Those technologies showing promise on a bench top scale
basis would be recommended for field trials at member
institutions. Field trial demonstration testing would be in
accordance with a protocol to be developed by the End of Pipe
Alternatives Subcommittee.
Minutes of November
30, 1994 Meeting:
Only one hospital had
responded to the Subcommittee's request for information
regarding historical wastewater characteristics from their
facility in advance of the meeting (ref. minutes dated November
16, 1994). It was agreed, therefore, that the request for this
information would be repeated. To help facilitate data
transmission, it was agreed that a form would be prepared and
distributed to the membership.
NOTE: Action
required by any participating member institution: Information
regarding typical wastewater discharge characteristics from your
facility to the MWRA sewerage system should be reported on the
attached form and returned (mail or fax) as soon as possible but
not later than December 9, 1994. The Subcommittee
suggests that members compile available results from recent MWRA
SMART reports submitted under Industrial User Discharge Permits.
All submitted reports will be sanitized (host facility name
and identifying information removed) prior to distribution. This
information will be compiled for reviewed at the next regularly
scheduled meeting of the Subcommittee. Please route this
request to the attention of your Facilities Engineer or other
staff member, as appropriate, immediately.
Depending upon the
response received to this second request, the Subcommittee may
seek to gain the information it needs via public records such as
those maintained in the MWRA's data base via SMART reports. Pat
Kelley agreed to look into this possibility in advance of the
Subcommittee's need to exercise the option.
The Subcommittee
discussed the possibility of conducting a tour of a local
industry subject to the MWRA regulations that had installed an
Industrial Wastewater Pretreatment (IWWT) system in order to
help ensure consistent compliance. The purpose of the tour is to
gain perspective on the types, extent and rigors involved in
supporting the continuous operation of an end-of-pipe IWWT
system in conjunction with a waste minimization program. To this
end, arrangements for a tour of the facilities of Altron, Inc.,
One Jewel Drive, Wilmington, MA on January 11, 1995 beginning at
10:00 AM were made. Since the tour is being hosted by an
industry outside of the MASCO Workgroup, advance registration
for this tour is required.
Minutes of December
14, 1994 Meeting:
Due to the late mailing
of the previous meeting's minutes, no further response to the
Subcommittee's previous requests for historical effluent quality
information had been received from the membership. Pat Kelley
reported that the MWRA would initially prefer that the
membership forward the required information to the Subcommittee
rather than have the Subcommittee secure the information by
accessing public (i.e., MWRA files). Accordingly, the
Subcommittee decided to wait to see what level of response
occurs thru the end of the year before formulating any
alternative measures to secure the required data.
Newton-Wellesley
Hospital reported that it had been approached by Ntec, Inc.
recommending the installation of a full scale portable waste
treatment system for volume reduction of presently containerized
waste. Should this system become operational, the Subcommittee
discussed the preparation of a testing protocol for the system
which would allow a full engineering assessment of performance.
As additional details become available, Jim Toma agreed to keep
the Subcommittee informed of any progress.
Some discussion on the
continued inclusion of "Bypass" arrangements into the
design of IWWT systems by certain area engineering firms ensued.
Bob Gingras indicated that, with the delegation of the State's
Industrial Sewer Connection Permitting program (314 CMR 7) to
the MWRA on October 8, 1993, the State had dropped their
requirement for engineering design plans review and approval {MGL
21, Section 27(13)}, as well. Since the only remaining approval
authority for an IWWT system appears to be the plumbing
inspector (for compliance with the provisions with 248 CMR 2.13
which does not prohibit the use of a
"by-pass"), it appears as though these devices are
continuing to be installed. Though it is understood that the
MWRA does not "approve" the design documents for
proposed IWWT system, Pat Kelley indicated that he would check
with the MWRA concerning their policy when encountering a
"by-pass" arrangement either during the design phase
or during field inspections and will report back to the
Subcommittee.
Minutes of January
4, 1995 Meeting:
In spite of the
December 19, 1994 Special Mailing by MASCO, no further response
to the Subcommittee's previous requests for historical effluent
quality information had been received from the membership. The
Subcommittee decided, therefore, to forward information that had
been previously submitted by one of its members to vendors for
use in developing systems for evaluation.
In an effort to help
augment this data base without incurring special analytical
costs to do so, Pat Kelley agreed to look into the possibility
of scheduling periodic MWRA compliance monitoring at member
hospital facilities over the next couple of months and expanding
the list of normally analyzed pollutants to include all of the
parameters appearing on the IWWT Subcommittee's questionnaire.
Since the sampling has to be done anyway, this method of data
collection would make the most sense plus the MWRA might be
willing to absorb the cost of the additional pollutant parameter
determination. Note that if the MWRA agrees to this
request, member institutions may wish to volunteer their sites
for this monitoring. By doing so, they will gain specific
additional information about current wastewater characteristics
as well as satisfy an ongoing regulatory obligation.
Jim Toma provided the
Subcommittee with follow-up information (proposal) received from
NTEC, Inc. relative to the installation of an industrial
wastewater pretreatment system for mercury removal to less than
1.0 ppb. The proposal details requirements of the performance
guarantee, terms and conditions. The Subcommittee directed Earth
Tech to place the information on file for future reference.
A presentation was made
by Water Systems Inc. of Newton, MA:
Mr. Joe Aliotta
explained that his firm is an Applications Engineering Company
that could provide turn-key IWWT system. He explained that his
concept to address the Hospital's current mercury problem was to
reduce flow rates in contributing locations to minimal levels,
then to apply sequential physical separation processes to
produce a permeate stream capable of ultimately being recycled
back to the facility. Mr. Aliotta claimed that he has
successfully applied combinations of simple filtration,
ultrafiltration\microfiltration, nanofiltration and reverse
osmosis to such application in the metal finishing and printed
circuit board industries though he indicated that he had not
done so in a hospital or research facility setting.
Water Systems, Inc.
represents a wide variety of equipment manufacturers from which
they purchase technological components and build site specific
IWWT systems depending upon the objective desired. A packet of
information was provided which will be maintained on file for
future reference.
Minutes of January
11, 1995 Meeting:
A tour of the
industrial wastewater pretreatment (IWWT) system that is
presently installed at Altron was completed with Messers. Tony
Cigliano and Peter Muto, Altron's Safety and Environmental
Managers, respectively, serving as our hosts. Mr. Matt Palance,
Vice President of Operations also provided some introductory
comments. Mr. Cigliano provided a brief overview of the
manufacturing processes which contribute contaminated wastewater
to the IWWT system then he and Mr. Muto proceeded to describe
the various components and functions of the installed systems.
The IWWT system
occupies approximately 10,000 square feet of the overall 180,000
square foot manufacturing complex and pretreats some 100,000
gallons of raw wastewater each day before discharging to the
MWRA Sewerage System. The installed IWWT system has been rated a
Grade 4-I plant by the DEP and is run by a staff which includes
eight (8) licensed operators (minimum staffing). The IWWT system
employs pH adjustment, complex bond destruction using
conventional (hydroxide) and advanced (DTC) chemistry,
precipitation, clarification/sedimentation, membrane (cross flow
microfiltration) separation, depth filtration, ion exchange and
electrolytic recovery. The primary objective of the process is
to maintain compliance with the MWRA's pretreatment standards
for lead (0.2 mg/l) and copper (1.5 mg/l). Mercury was not
stated to be an ongoing concern.
The capital cost of the
installed equipment components is in the $1 to $2 million range.
The operating budget of the IWWT system approaches $1,000,000
(chemicals, waste disposal, compliance fees and staff labor)
annually.
Minutes of January
25, 1995 Meeting
Earth Tech reported
that two (2) additional responses to the Subcommittee's request
for historical monitoring data had been received since the last
mailing. As agreed, that information along with data previously
submitted had been compiled and was in process of being
forwarded to vendors for use in developing systems for
evaluation. To date, an information packet had been sent to US
Filter.
Pat Kelley reported
that the MWRA had initiated "Special Sampling" at
three (3) facilities and that analytical data would be
forthcoming. Jim Toma expressed some concern over the
representative nature of the sampling since, to his knowledge,
one sample set had been taken from a laundry discharge and two
other sample sets had been obtained from laboratories but at
institutions that are relatively low flow dischargers. Jim
requested that Pat obtain clarification from the MWRA, TRAC on
how this data might be used against an institution if problems
with respect to MWRA regulatory compliance, beyond the mercury
issue, are discovered. For example, if an institution is not
required by its IUDP to analyze its discharge for TPH but the
"Special Sampling" shows something in excess of 15
mg/l, how would the MWRA handle it? Pat is to look into and
report back to the Subcommittee.
In view of the three
sites sampled thus far, the Subcommittee again requested that
the MWRA perform "Special Sampling" at additional
facilities so that a better cross section of wastewater
characterization data might be compiled.
Analytical data
generated around a pretreatment system that has been installed
on the waste stream produced by a medical waste incinerator fume
scrubber was entered into discussion. Though promising, this
system, which employs sulfur impregnated activated carbon for
mercury removal, has not been able to consistently attain the
MWRA's stipulated 1.0 ppb enforcement limit. The Subcommittee
decided to make arrangements to have the manufacturer of the
system make a presentation at the next regularly scheduled
meeting.
A presentation was made
by Wheelabrator\Memtek of Billerica, MA:
Mr. Stratton Tragellis
explained that his firm manufactures turn-key IWWT systems which
may employ advanced chemistry, membrane separation and/or ion
exchange technology. He explained that the chemistry employed on
a particular wastestream is tailored, via pilot testing, to the
particular application in order to convert all regulated
pollutants to a filterable form. After this occurs, the solids
are removed via a proprietary membrane microfilter having an
effective pore size of 0.1 to 10 microns. Mr. Tragellis
explained certain related experience in mercury removal projects
at Duracell battery, at the Fort Dix military installation and
at the University of Illinois at Urbana.
The membrane is largely
unaffected by bleach, organic material, oil/grease etc. but has
an operating temperature limitation of 140 F and could be
affected by solvents if present at concentrations in excess of
1% (10,000 mg/l). Each membrane stack is capable of processing
between 2-5 gpm and costs about $2,500. Each membrane is
warranted for 3 years. Stratton explained that Wheelabrator has
installations treating flows of up to 600 gpm. A packet of
information was provided to all Subcommittee members which will
be maintained on file for future reference.
Minutes of February
8, 1995 Meeting
Pat Kelley reported
that, per the Subcommittee's request, the MWRA had completed
"Special" sampling at two additional facilities
bringing the total to five. Analytical data will be provided to
the Subcommittee following its receipt and verification for
accuracy.
Performance testing
results of the Ntec, IWWT system that had been recently
installed at BU was provided by Pat Kelley under the name of
Solmetex, Inc.. This data was not discussed during the meeting
since the Solmetex, Inc. name was not recognized. After
reviewing, members should raise any questions for discussion at
the next meeting.
Jim Toma reported that
he had been provided with final proposals by Water Systems, Inc.
for the installation of a field demonstration IWWT system
designed for use on the laundry discharge stream and by B.G.
Wickberg, Inc. for the installation of a field demonstration
IWWT system designed for use on a laboratory discharge stream.
Jim indicated that once these tests were initiated, he would
relay obtained information to the Subcommittee, following
receipt.
The Subcommittee heard
a presentation by Henry Hadley of B.G. Wickberg, Inc. of N.
Quincy, MA:
Analytical data
generated around a pretreatment system that has been installed
on the waste stream produced by a medical waste incinerator fume
scrubber liquor discharge since May of 1994 was reviewed. The
system utilizes approximately 16 cubic feet of Mersorb
(elemental sulfur impregnated activated carbon) in two
sequencing reactors of approximately 55 gallon individual
capacity. Hydraulic loading to the system ranges between 3 and 5
gpm but varies as a function of scrubber/incinerator operation.
Influent pH to the system can also vary (5.5 to 10.5 s.u.) but
was not reported to be problematic to system performance unless
unusually elevated alkaline conditions were encountered (would
tend to strip adsorbed material).
Mr. Hadley explained
that the carbon, by its nature, would tend to directly adsorb
mercury which was organically bound while the sulfur would tend
to reduce ionic mercury to an insoluble mercuric sulfide onto
the surface of the carbon media where it would be filtered out.
Reactor kinetics, though not defined, were described as
"slow" (design detention time unavailable for
alternative system sizing). Though it appears capable of
removing a significant percentage of influent mercury regardless
of concentration (up to 1 mg/l), the available data did not
indicate operating efficiencies below 1.0 ppb. This was also
true following attempts to enhance system performance this
system via the installation of KDF resin in an attempt to
further remove ionic mercury.
Minutes of February
22, 1995 Meeting:
Pat Kelley provided
partial results of the "Special Sampling" that had
been completed by the MWRA at the request of the Subcommittee.
Analytical data from the remaining four locations where this
"Special Sampling" has been performed will be provided
to the Subcommittee following its verification for accuracy by
the MWRA. Pat indicated that all data will likely be available
by March 22, 1995. It was agreed that the information gained
from this sampling will be distributed to system suppliers
following the Subcommittee's next meeting on March 8, 1995.
Though realizing that
it was moving somewhat outside of its primary focus area, the
Subcommittee decided that a presentation on the regulatory
impacts of the Clean Air Act (Massachusetts and Federal) would
be needed in order to fully understand the ramifications of a
closed loop system using evaporative technology. Bob Gingras
agreed to have a representative of Earth Tech's Air Compliance
and Permitting Division attend the Subcommittee's next meeting
to provide this perspective.
Minutes of March 8,
1995 Meeting
Pat Kelley provided the
results of additional "Special Sampling" that had been
completed by the MWRA at two more locations. Analytical data
from the remaining two locations where this "Special
Sampling" has been performed will be provided to the
Subcommittee following its verification for accuracy. Pat
indicated that all data will likely be available by March 22,
1995. Earth Tech subsequently compiled and distributed the
information to all system suppliers that the Subcommittee has
interviewed to date.
The Subcommittee next
heard a presentation by Dr. Stephen J. Kmiotek, P.E. of Earth
Tech regarding the implications of evaporative technology under
the Clean Air Act (Massachusetts and Federal) when attempting to
"close the loop":
The institutions, as a
group, generate wastewater containing an estimated total of 0.41
ounces per day, or a total of nine (9) pounds per year of
mercury. The use of an evaporator (either fuel-fired or
atmospheric) had been suggested as one possible method to treat
the wastewater and remove the mercury. In summary, evaporators
are routinely used to reduce the moisture content of sludges and
their permitting is relatively straightforward. The
Massachusetts DEP requires permits (or "air plans
approvals") for the construction, installation, and
operation of sources of air emissions under the provisions of
310 CMR 7.02. These include fuel-burning sources (including a
fuel-fired evaporator) and sources of process emissions. Certain
sources are exempt from this requirement, including:
- natural gas and
distillate oil fired combustion sources with a heat input
rating of less than 10 MMBtu/hr; and
- sources that emit
less than 2,000 pounds per year of a pollutant.
The DEP has the authority
to require a permit for a source even if it meets an exemption
criteria if they believe the source has the potential to impact
the environment. Under new Federal regulations, sources with
mercury emissions of more than 200 pounds per year would be
considered a major source of mercury emissions and would be
subject to additional permitting. Here, it is likely that the
DEP would require a permit for a potential source of mercury
emissions (though a permit would not necessarily be required for
the combustion portion if the evaporator had a capacity of less
than 10 MMBtu/hr). Given the toxicity of mercury, the DEP would
likely require submittal of a non-major comprehensive plans
approval application, which consists of:
- A narrative
description of the project, including process description,
production rates and restrictions, emission rates and
descriptions, descriptions of the coatings and stains used,
BACT analysis, and proposed permit conditions and
recordkeeping requirements;
- Permit forms,
including an emission summary form; a data form for process
emissions; and a BACT summary form;
- Necessary supporting
documentation, including calculations, process flow diagram,
topographic map, plot plan, roof plan, floor plan, MSDSs,
and standard operating and maintenance procedures; and
- P. E. certification;
and
- A $1,100 filing fee.
In addition to permits,
the level of emissions are regulated by the DEP. All new and
modified sources in Massachusetts must implement, at minimum,
Best Available Control Technology (BACT). For an evaporator,
BACT would likely require the use of low-NOx burners, process
control to minimize mercury volatilization, and a mist
eliminator (though a rigorous analysis would have to be
conducted). A demonstration using atmospheric dispersion
modeling would have to be conducted to ensure that mercury
emissions from the evaporator did not result in an increase in
the ambient mercury concentration of the following levels:
| Form |
Maximum 24-hour
concentration (g/m3) |
Maximum annual
concentration (g/m3) |
| Elemental
Mercury |
0.14 |
0.07 |
| Inorganic
Mercury |
0.14 |
0.01 |
| Methyl Mercury |
0.003 |
0.0014 |
If mercury emissions
exceeded 200 pounds per year, the evaporator would be considered
a major source of mercury emissions and would be subject to more
stringent control requirements.
Minutes of March 22,
1995 Meeting:
Pat Kelley provided the
balance of results of "Special Sampling" that had been
completed by the MWRA. Bob Gingras subsequently compiled the
information into the Subcommittee's data base. Due to time
constraints, this updated information will not be released to
system suppliers via a special mailing. Rather, it will be
adapted for use in the Subcommittee's Report and/or will be
shared by Subcommittee members as they follow-up with vendors
during negotiations for on-site testing (see item below).
Bob Gingras provided
the following update regarding the responses (including type)
received following issuance of the vendor letters on March 9,
1995:
| Water Stop |
No response |
| Waters Systems |
No response |
| U.S. Filter |
Telephone
response - positive interest indicated |
| B.G. Wickberg |
Telephone
response - positive interest indicated |
| Solmetex\Ntec |
Telephone
response - positive interest indicated |
| Wheelabrator\Memtek |
No response |
The Subcommittee
assigned responsibility for future coordination of the details
of on-site pilot trials with the vendors expressing interest as
follows:
| U.S. Filter |
Bruce McCoy (DH) |
| B.G. Wickberg |
Jim Toma (N-W) |
| Solmetex\Ntec |
Doug Larson (GZA-NEMC) |
| Wheelabrator\Memtek |
Cheryl
Kosegarten (MGH) |
A status update report
will be provided by each at the next Subcommittee meeting.
The Subcommittee
reviewed, discussed and approved, for issuance, a Preliminary
Progress Report that had been prepared at the request of
the Steering Committee.
In an effort to help
augment the Subcommittee's current data base regarding the
nature and characteristics of its members' wastestreams, a
request has been made to the MWRA by the Steering Committee for
a summary of the SMART mercury data base for the third and
fourth quarters of Calendar 1994. This information is viewed as
critical in assessing progress made by the Workgroup, as a
whole, but will also prove invaluable to the End of Pipe
Alternatives Subcommittee as a more "Real Time"
statement of the situation which still exists within the
membership. Upon receipt, this information will be compiled and
distributed to the Subcommittee via minutes.
Minutes of April 5,
1995 Meeting:
Bob Gingras reported
that SMART mercury data from selected SIUs for the third and
fourth quarters of Calendar 1994 had been received from the MWRA
since the last meeting. This information was entered into
discussion during the meeting but, due to its volume, will be
retained on-file rather than be distributed via meeting minutes.
The Subcommittee requested that Bob Gingras complete an analysis
of the raw data and compile a spreadsheet to summarize the
information (by permit number, not name of facility) presented
in the entire database. This spreadsheet is to be available for
discussion at the next Subcommittee meeting.
As a follow-up to the
last meeting's discussion relative to the availability of
sampling support by the MWRA during field pilot trials, Bob
Gingras reported that nothing "Official" (verbal or
written) had been received from the MWRA. Pat Kelley reported
that the matter had been discussed internally, however, and that
the MWRA would be able to commit resources as follows:
After July 1st: three
(3) sites each with up to four (4) sampling taps
Before July 1st: Site
specific depending upon available resources.
Ben Johnson reported
that a new IWWT system has been configured and installed at
South Shore Hospital and that initiation trials (5 consecutive
days) are currently scheduled for the week of April 17, 1995.
The Subcommittee requested that the MWRA conduct testing at this
site as its first effort. To accommodate, Ben Johnson is to have
B.G. Wickberg prepare and submit a flow schematic of the system
to Earth Tech who will, in turn, prepare a sampling protocol
which will identify sampling locations and analytical parameters
required for evaluating system performance (pH, TSS, TDS,
mercury-total, mercury-dissolved). Bob will then provide this
information to Pat Kelley who will coordinate the sampling and
analytical effort within the MWRA.
The following reports
were given regarding the status of negotiations with vendors
relative to on-site pilot trials:
U.S. Filter - Bruce
McCoy (DH): A meeting with a representative of US Filter has
been held since the last meeting. Details on a field
demonstration trial are being worked out with a letter from US
Filter promised by the week of April 10, 1995.
B.G. Wickberg - Jim
Toma (N-W): Nothing to report.
Solmetex\Ntec - Doug
Larson (GZA-NEMC): See attached report.
Wheelabrator\Memtek
- Cheryl Kosegarten (MGH): Nothing to report.
Manchester
Corporation - Charlie Storella (DFCI): Charlie reported that
he had been contacted by Mr. Dan Adner who expressed interest in
performing a field trial. Charlie is to work out the details and
report back to the Subcommittee.
Minutes of April 19,
1995 Meeting:
Bob Gingras reported
that SMART mercury data from selected SIUs for the third and
fourth quarters of 1994 had been received from the MWRA since
the last meeting. A "sanitized" spreadsheet of the
information (names and permit numbers of SIUs suppressed) was
distributed for discussion. Bob also reported that additional
information for Fiscal 1993, 1994 and 1995 has been requested
from the MWRA and will be similarly manipulated to show progress
being made since formation of the Workgroup. An update to
progress on this task will be provided at the next Subcommittee
meeting.
Ben Johnson provided an
update of the status of sampling to be completed around the new
IWWT system that has been installed at South Shore Hospital. As
was discussed at the last meeting, a flow diagram was provided
and a suggested field sampling protocol had been prepared by
Earth Tech for implementation by the MWRA. Ben reported that
sampling will actually be initiated during the week of April 24,
1995 using a subcontract laboratory. The MWRA will likely
perform their testing during the first week of May. Ben agreed
to share all data received with the Subcommittee.
The following reports
were given regarding the status of negotiations with vendors
relative to on-site pilot trials:
U.S. Filter - Bruce
McCoy (DH): No progress.
B.G. Wickberg - Jim
Toma (N-W): Final negotiations underway. A written report is
expected by May 3, 1995.
Solmetex\Ntec - Doug
Larson (GZA-NEMC): No report.
Wheelabrator\Memtek
- Cheryl Kosegarten (MGH): Letter received but no apparent
willingness to perform on a low/no cost basis. Cheryl indicated
that, though she will continue to pursue these negotiations, MGH
has decided not to serve as a host site for pilot testing.
Manchester
Corporation - Charlie Storella (DFCI): Letter of interest
has been received.
Jim Toma distributed a
copy of the outline of the "Mercury How To Guidebook"
being prepared by the MWRA Operations Subcommittee. Pat Kelley
provided the Subcommittee members with a copy of the MWRA's
recently published "Contingency Plan". Copies of both
documents will be retained on file at Earth Tech on behalf of
the Subcommittee.
Minutes of May 3,
1995 Meeting:
Bob Gingras reported
that additional SMART mercury data from selected SIUs for the
period 1993 thru 1995 has been received from the MWRA since the
last meeting and is in process of being reviewed. A summary of
data compiled, to date, was discussed in order to show
preliminary trends, as follows:
| Period Reviewed |
Data Points |
Total Flow, MGD |
Mercury, ounces |
| Fiscal
1994 |
230 |
0.83 |
2.36 |
| Fiscal
1995, Q1&Q2 |
452 |
1.18 |
0.64 |
| Fiscal
1995, Q1&Q2* |
452 |
0.97 |
0.31 |
| Fiscal 1995,
Q3&Q4 |
118 |
0.82 |
0.47 |
*Reflects NDs zero'd out
and actual flows based on installed meters, where available
Once data manipulation
is complete, "sanitized" spreadsheets (names and
permit numbers of SIUs suppressed) will be incorporated into the
final Subcommittee Report.
Ben Johnson provided an
update of the status of sampling being completed around the new
IWWT system that has been installed at South Shore Hospital.
Preliminary data is starting to trickle in but was not able to
be discussed in a meaningful way during the meeting. As more
information becomes available, Ben will send to Bob Gingras at
Earth Tech for incorporation into the Subcommittee files.
The following reports
were given regarding the status of negotiations with vendors
relative to on-site pilot trials:
U.S. Filter - Bruce
McCoy (DH): No progress
B.G. Wickberg - Jim
Toma (N-W): Water Systems, Inc. will attempt the treatment
of laundry discharges. B.G. Wickberg will attempt the treatment
of clinical laboratory wastewater. Details were not available
but Jim agreed that support, e.g., sampling protocol, by the
Subcommittee would be welcome.
Solmetex\Ntec - Doug
Larson (GZA-NEMC): Nothing new since last report.
Wheelabrator\Memtek
- Cheryl Kosegarten (MGH): No progress.
Manchester
Corporation - Charlie Storella (DFCI): No progress
The Subcommittee
discussed the concept of the final Report with presentations
made by Messers. Storella, McCoy and Gingras relative to content
and format. The Subcommittee decided that there would be no need
for a meeting on May 17, 1995 since time would be better spent
in preparing the manuscript. A draft of the Report will be
distributed to the members of the Subcommittee prior to the next
meeting where constructive comments and suggestions will be
received for discussion prior to its being finalized.
A
spreadsheet which summarizes presentations made to the
Subcommittee by the various equipment suppliers and attempts to
categorize the systems according to technology follows.
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